Quantum Physics For Dummies
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In quantum physics, you can determine the radial part of a wave function when you work on problems that have a central potential. With central potential problems, you’re able to separate the wave function into a radial part (which depends on the form of the potential) and an angular part, which is a spherical harmonic.

You can give the radial part of the wave function the name Rnl(r), where n is a quantum number corresponding to the quantum state of the radial part of the wave function and l is the total angular momentum quantum number. The radial part is symmetric with respect to angles, so it can’t depend on m, the quantum number of the z component of the angular momentum. In other words, the wave function for particles in central potentials looks like the following equation in spherical coordinates:

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The next step is to solve for Rnl(r) in general. Substituting

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from the preceding equation into the Schrödinger equation,

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gives you

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Okay, what can you make of this? First, note that the spherical harmonics are eigenfunctions of L2 (that’s the whole reason for using them), with eigenvalue

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So the last term in this equation is simply

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That means that

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takes the form

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which equals

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The preceding equation is the one you use to determine the radial part of the wave function, Rnl(r). It’s called the radial equation for a central potential.

When you solve the radial equation for Rnl(r), you can then find

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because you already know

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So, you’re simply finding the solution to the radial equation.

About This Article

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About the book author:

Steven Holzner is an award-winning author of technical and science books (like Physics For Dummies and Differential Equations For Dummies). He graduated from MIT and did his PhD in physics at Cornell University, where he was on the teaching faculty for 10 years. He’s also been on the faculty of MIT. Steve also teaches corporate groups around the country.

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