Multiple Bonds in Covalent Bonding
Covalent bonding is the sharing of one or more electron pairs. In many covalent bonding situations, multiple chemical bonds exist — more than one electron pair is shared. (In hydrogen and the other diatomic molecules, only one electron pair is shared.)
Nitrogen is a diatomic molecule in the VA family on the periodic table. Nitrogen has five valence electrons, so it needs three more valence electrons to complete its octet.
A nitrogen atom can fill its octet by sharing three electrons with another nitrogen atom, forming three covalent bonds, a so-called triple bond. The triple bond formation of nitrogen is shown in the following figure.
Triple bond formation of nitrogen.
A triple bond isn’t quite three times as strong as a single bond, but it’s a very strong bond. In fact, the triple bond in nitrogen is one of the strongest bonds known. This strong bond is what makes nitrogen very stable and resistant to reaction with other chemicals.
It’s also why many explosive compounds (such as TNT and ammonium nitrate) contain nitrogen. When these compounds break apart in a chemical reaction, nitrogen gas is formed, and a large amount of energy is released.
Carbon dioxide is another example of a compound containing a multiple bond. Carbon can react with oxygen to form carbon dioxide. Carbon has four valence electrons, and oxygen has six. Carbon can share two of its valence electrons with each of the two oxygen atoms, forming two double bonds. These double bonds are shown in the following figure.
The formation of carbon dioxide.
Chemistry Glossary
Archimedes Principle
A principle discovered by the Greek mathematician Archimedes which states that the volume of a solid is equal to the volume of water it displaces.
Chemistry Glossary
atomic number
The number of protons in the nucleus of an atom.
Chemistry Glossary
Bohr model
A model of atomic structure developed by Niels Bohr, a Danish scientist. In this model, electrons occur in orbits of differing energy levels around the nucleus of an atom.
Chemistry Glossary
condensation
The change in the physical state of matter from a gaseous state to a liquid state.
Chemistry Glossary
deposition
The change in the physical state of matter from a gaseous state to a solid state without ever becoming a liquid. The reverse of sublimation.
Chemistry Glossary
electrolytes
Substances that can conduct electricity either in the molten state or when dissolved in water.
Chemistry Glossary
electron configuration notation
A method used by chemists to represent electrons in bonding and chemical reactions.
Chemistry Glossary
electronegativity
A measure of an atom’s strength to attract a bonding pair of electrons to itself.
Chemistry Glossary
energy level diagram
A method used by chemists to diagram the electrons for an atom (including orbitals and subshells) in bonding and chemical reactions.
Chemistry Glossary
heterogeneous mixture
A mixture whose composition varies from position to position within a sample.
Chemistry Glossary
homogeneous mixture
A mixture whose composition is the same from position to position within a sample.
Chemistry Glossary
isotopes
Atoms of the same element that have varying numbers of neutrons.
Chemistry Glossary
mass number
The sum of the protons and neutrons in a particular isotope; also called atomic weight.
Chemistry Glossary
nonelectrolytes
Substances that do not conduct electricity in the molten state or when dissolved in water.
Chemistry Glossary
nuclear fission
A nuclear reaction in which an atom’s nucleus splits into smaller parts.
Chemistry Glossary
nuclear fusion
A process in which lighter nuclei of atoms join together into a heavier nucleus; essentially the opposite of nuclear fission.
Chemistry Glossary
nuclear reaction
Any reaction that involves a change in nuclear structure.
Chemistry Glossary
periodic table
A table that displays all known chemical elements in an arrangement that is based on the properties of the elements; changes over time as new elements are discovered.
Chemistry Glossary
quantum mechanical model
A model of atomic structure that is based on mathematics and can be used to explain observations made on complex atoms.
Chemistry Glossary
radioactivity
The spontaneous decay of an unstable nucleus in an atom.
Chemistry Glossary
SI system
A worldwide measurement system that is based on the older metric system. The SI comes from the French Systeme International.
Chemistry Glossary
sublimation
The change in the physical state of matter from a solid state to a gaseous state without ever becoming a liquid (such as dry ice).
Chemistry Glossary
valence electrons
The electrons in the outermost energy level of an atom, the farthest away from the nucleus.
