How to Add Data to Data Lists Using the Excel 2013 Form Button
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Click the Customize Quick Access Toolbar button at the end of the Quick Access toolbar and then click the More Commands item at the bottom of its drop-down menu.
Excel opens the Excel Options dialog box with the Quick Access Toolbar tab selected.
The Form command button you want to add to the Quick Access toolbar is only available when you click the Commands Not in the Ribbon option on the Choose Commands From drop-down list.