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Finding the Total Energy Equation for Three-Dimensional Free Particle Problems

At some point, your quantum physics instructor may want you to find the total energy equation for three-dimensional free particle problems. The total energy of the free particle is the sum of the energy in three dimensions:

E = Ex + Ey + Ez

With a free particle, the energy of the x component of the wave function is

image0.png

And this equation works the same way for the y and z components, so here’s the total energy of the particle:

image1.png

Note that kx2 + ky2 + kz2 is the square of the magnitude of k — that is,

image2.png

Therefore, you can write the equation for the total energy as

image3.png

Note that because E is a constant, no matter where the particle is pointed, all the eigenfunctions of

image4.png

are infinitely degenerate as you vary kx, ky, and kz.

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